SBS - Thermoplastic polymers, elastomers and additives

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SBS

Thermoplastics > Styrenics
SBS - Copolymer styrene-butadiene-styrene
Products range



In Mexpolimeros we offer a wide range of SBS elastomers and their compounds developed according to their needs, ensuring quality products and service. Te have grades and compounds, opaque, translucent, crystals, compounds of low densities products for industrial applications with excellent characteristics of environmental resistance, such as oil and grease, acids and solvents, high temperatures. XPRENE B is divided into a wide range of products such as soft touch, expandable, high temperature resistant, low compression set, halogen flame retardant and many other specialty categories. The wide range of additives and olefins incorporated into our compounds have allowed us to create a vast array of products that can replace either the PVC elastomer used in footwear or natural rubber gaskets and seals manufactured.



Block copolymer styrene butadiene



SBS block copolymers , also known as Styrene-butadiene-styrene (SBS) thermoplastic elastomers , flows easily into the processing at different temperatures and act as elastic rubbers reinforced under normal application conditions. It is a type of copolymer called a block copolymer. Its backbone is composed of three segments; a sequence of repeating units of styrene, a labeling sequence butadiene repeat units and topped with another block of styrene units to give a block copolymer of styrene-butadiene-styrene (SBS).
Block copolymers of styrene-butadiene are polymerized in solution and have different, linear, radical and multiarmed structures. They are free flowing materials showing different viscosities to adapt their properties to multiple applications that can be used. The linear degrees of low molecular weight offer very good flowability, are prized for their transparency and processability. The radial degrees showed resistance molding, and offer superior mechanical properties with high performance modification. The multilink degreesshow a combination of low viscosity with temperature resistance. This performance makes them suitable for a wide range of technical applications such as compositions, adhesives and sealants, asphalt modification for roads and pavements waterproofing membranes. They are also used in applications Shoeleather and polymer modification. SBS Elastomer meet different food contact applications. The typical presentation of these products can range from soft lumps versions powder. Block copolymers of styrene-butadiene have different, linear, radical and multiarmed structures. SBS linear low molecular weight provide good transparency and processabilityBuende flow thanks to the radial degrees provide  superior mechanical properties at high yield modification and increased resistance of cast iron, the degree multi-arm provide a combination of low viscosity and better temperature resistance.



Symbols




  • SBS
  • TPE-S
  • TPS
  • S-B-S
  • Copolimero- styrene butadiene styrene
  • Poly(styrene-butadiene-styrene)
  • Copolimero-estireno-butadieno-estireno
  • Poly(styrene-butadiene-styrene)

           
Properties



  • Shore A hardness of 30 to shore D40
  • Operating Temperature -50 to 70 ° C
  • Weak to atmospheric agents
  • Good abrasion resistance
  • easy processability
  • Easy coloring
  • Compatible with PS, PP, EVA
  • Grades for food contact
  • high transparency
  • Nonhygroscopic, pre-drying is not necessary
  • It allows coloring directly during the process
  • Some special grades have high abrasion resistance
  • 100% recyclable


Physical and mechanical properties



Polystyrene is a tough hard plastic, and this gives SBS thermoplastic durability. Polybutadiene is rubbery, and this gives SBS elastomer its rubber-like properties. In addition, the polystyrene chains tend to cluster. When a group of styrene SBS molecule binds to a group, and the other strand of the same polystyrene SBS molecule binds to another group, the different groups are attached with rubbery polybutadiene chains. This gives the material the ability to retain its shape after being stretched.At room temperature (below the glass transition temperature of polystyrene) adding styrene block cluster (domains) to act as physical crosslinks rigid, maximizing the high elastic properties of the butadiene block. At elevated temperatures the styrene domains are unraveled and the polymer becomes a, suitable for extrusion and injection molding thermoplastic melt. The elastic properties of stretch and recovery SBS elastomer match conventional vulcanizate, but the advantage is that there is a stage of "healing", and the processing time and power consumption are greatly reduced. Also the SBS can be processed from solution.

However the thermoplastic SBS has degradation problems at high temperatures and butadiene content makes it prone to oxidation and wear, without suitable antioxidants. The SBS offers excellent surface friction coefficient, low permanent deformation, a tensile strength. The material can be temporarily deformed by compression or elongation, but when these forces cease, the material returns to its original shape . XPRENE B thermoplastic elastomers and have elastomeric properties but are processed as plastics.



Thermal properties



The glass transition temperature (Tg) of the polybutadiene blocks is typically -90 ° C, while the Tg of the polystyrene blocks is + 100 ° C. Therefore, at any temperature between -90 ° C and + 100 ° C, SBS act as an elastomer physically crosslinked. The operating temperature is guaranteed from -55 ° C to + 70 ° C.These unsaturated TPE low tend to have weatherability and quite poor UV and a moderate stability at elevated temperatures due to their double bonds. They must be tested for possible yellowing or brittleness. This group of products is sometimes also described as TR. At high melting temperatures and during recycling, it is important to be careful with undesired bonds. For this family of products is very important in the footwear industry.



Electrical properties



SBS elastomer is usually good insulator with high electrical resistivity relative, being nonpolar. However, the electrical properties of the compounds of XPRENE B are dependent on the ingredients used in the mixture of the elastomer base. Antistatic compounds do SBS and even conductive by the incorporation of sufficient amounts of graphite, special types of carbon black, certain metal powders or polar products in the rubber mixture. However, the conductivity obtained by these means does not resemble that of metals.It is not possible to make a clear distinction between insulating elastomer, antistatic and drivers. SBS polymers generally having a resistivity below 10² Ohms are considered conductors; between 10¹³ and 10² Ohms, antistatics; and above 10¹³ Ohms, insulators.






Optical properties


One of the features of a two - phase system is that light is scattered when passing from one phase to another, resulting in different levels of transmission of light, in the case of SBS polymer also have high transparency degrees.


Chemical properties



SBS polymers well resist stress crack (stress cracking) acid, hydroxides, methanol and ethanol, absorb oil, fats, aliphatic hydrocarbons. Instead not Reisten polar hydrocarbons, aromatic hydrocarbons, carboxylic acid, gasoline, oil ASTM No 1 Paraffiico, ASTM # 3 oil Aromatic, toluene and benzene. Good water resistance but poor resistance to water vapor. Low resistance to oils (animal and plant). The chemical nature unsaturated SBS rubber makes XPRENE B is sensitive to the action of heat from UV and ozone, but the use of special additives improves resistance to these environmental effect.



Polimerization



Block copolymers of styrene-butadiene is polymerized in solution, ys and is available a full portfolio of linear, branched and radial degrees. In the polymerization, the diblock copolymer styrene-butadiene living becomes a linear SBS triblock copolymer by subsequent addition of a difunctional coupling agent, whose amount can vary for different yields polymers coupled SBS and uncoupled SB. Alternatively, the addition of a coupling agent with a functionality of three or more leads to the formation of copolymer SBS radial blockWhose number of arms SB depends on the structure of the polyfunctional coupling agent. When styrene is added instead of the coupling agent, we refer to the polymerization SBS three stage copolymer leads to linear SBS. Finally, we must add a terminating agent to terminate the active chain ends. Chemical residues of termination reactions or coupling must be inactive to the antioxidant to prevent the yellowing of SBS copolymer.

Based on the above, it follows that the linear SBS can be obtained from the three stages, a polymerization process and the two stages, while the radial SBS can only be obtained from the polymerization process of the two stages. When the polymerization reaction of butadiene and styrene is carried out simultaneously in a batch reactor, a copolymer of SB type is obtained. In this case, the polybutadiene blocks and polystyrene are joined through a polymer chain portion (taper) in which a progressive variation of the composition is observed.The resulting lack of the second polystyrene block does not allow the mechanical properties of pure triblock copolymers, but improves other useful properties for adhesives and modifications bitumen.  Dry and oil extended grades are available in different forms: pellets, granules and powder.



Processability


The SBS belong to the class of thermoplastic elastomers having the mechanical properties of rubber at room temperature and thermoplastic processing capabilities.

The SBS polymers are rubbery without being crosslinked, so it is easy to process to achieve useful forms, usually processed more or less at 140 to 200 ° C. SBS resin can be easily molded by injection, extrusion or molding, of injection, blow molding, co-stapaggio, overmolding, 2K.


Overmolding - 2K



Adhesion to a wide range of polar and nonpolar substrates such as PP, PA, ABS, PC, PS, SAN, ASA, PC / ASA, PBT, PET, ABS / PC etc. also it has a very good adhesion to PE compared with SEBS and SEPS. For the selection process overmolding or 2K in certain TPEs vary the bond strength in the application, for example if the molding process is chosen for multi shot (multi-shot) compared to the insert molding, the first certain promotes increased binding strength or binding because the two materials melt joining state, while the latter gives a poor bond since one of the two materials (plastic) is superimposed on the other that is not cast (metal). So the selection process to be applied is a key to produce a high quality factor. Within the selection of material, It depends on the company and product handling, where one has to consider the characteristics of each material for the application of overmolded, as there are a variety of materials having different properties that provide softness, texture, adhesion, and wall thickness of the material. For the effect of the thickness is necessary to know the hardness of the material, for example when it has a TPE material with a low thickness (typically> 1mm) would be perceived harder and vice versa when there is more than 1mm thickness will feel smooth. To ensure a good link overmolding their searches a thickness in the range 1.5mm for most applications overmolding. since there are a variety of materials having different properties that provide softness, texture, adhesion, and wall thickness of the material. For the effect of the thickness is necessary to know the hardness of the material, for example when it has a TPE material with a low thickness (typically> 1mm) would be perceived harder and vice versa when there is more than 1mm thickness will feel smooth. To ensure a good link overmolding their searches a thickness in the range 1.5mm for most applications overmolding. since there are a variety of materials having different properties that provide softness, texture, adhesion, and wall thickness of the material. For the effect of the thickness is necessary to know the hardness of the material, for example when it has a TPE material with a low thickness (typically> 1mm) would be perceived harder and vice versa when there is more than 1mm thickness will feel smooth. To ensure a good link overmolding their searches a thickness in the range 1.5mm for most applications overmolding. 1mm) would be perceived harder and vice versa when it is thicker than 1mm will feel smooth. To ensure a good link overmolding their searches a thickness in the range 1.5mm for most applications overmolding. 1mm) would be perceived harder and vice versa when it is thicker than 1mm will feel smooth. To ensure a good link overmolding their searches a thickness in the range 1.5mm for most applications overmolding.



Compounds


The products of class XPRENE B is obtained by mixing in compoundSBS resin, oil, polystyrene, additives, and some grades have reinforcements of a continuous phase morphology. The SBS elastomeric phase gives the material the elastic properties and the softness, the PS plastic phase provides the material with the mechanical properties and hardness and is characteristics that it maintains at low temperatures, up to -45 ° C. The inclusion of a charge to a polymeric matrix can describe a compatibilization effect between immiscible or immiscible mixtures and thus also exhibit excellent electrical conductivity, hardness, rigidity, mechanical and thermal resistance, and even to provide bactericidal properties to the new material. Polymer melt mixing has been the fast track for the design of new resins that seek to combine the properties of SBS and PS, to reach the superiority of certain characteristics due to the synergy that they can present.



Applications


The granules SBS is very soft-looking rubber is mostly used in applications where mechanical performance and chemical characteristics are less important and in which the soft touch and the handle is valued. L as typical applications are, profiles, housewares, handles, knives, handles, fittings, feet, storage, to slip lfombras, slip inserts, knobs, buttons, seals, profiles, covers pedal, tools electrical, seals for cables, plugs and sockets, handles "soft touch" for various utensils, fist bicycle, motorcycle fist, biter,Grip pen, toothbrush, fishing baits, ball rehabilitation, medical mattress, overprinted soft edges on decks, boxes garden tools, knobs, dampers, fins, masks, caps, terminal, non - slip, housewares, caps , toys, appliances, sealing rings, cable glands, save-remote, furniture, glass cleaners, drain cleaners for sinks, legs, construction, seats, clothing doors, handles, seats, sorpresitas. The SBS pellets in the industry of shoes, insoles, soles, fences, boots in many transparent, matte shapes and bright , aged and any color. They are alsosuitable for a wide range of technical applications such as compositions, adhesives and sealants, asphalt modification for roads and pavements waterproofing membranes. They are also used in applications modifying the polymer, automotive, seals, carpets, seals FDA, coatings lids of bottles, conveyor belts, gum, hoses, rolls, insulators, polystyrenes, friction, technical articles, adhesives, castings , O - rings, paper and textile coatings, to mortiguadores for wood sheets, profiles backlashes, g uarniciones for sprinklers, flexible rubber components for bedsteads , bases stairs Scaffold or end pieces, rubber bumpers, door handles , flexible coverings, etc.



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sms, sobremolde, sociedad, soldadura de gas caliente, soldadura de p,ndulo, soldadura l ser, soldadura por aire caliente, soldadura por fricción (rotacional), soldadura por inducción, soldadura por infrarojos, soldadura por microonda, soldadura por vibración, soldadura ultrasónica, soldadura, soldadura por alta frecuencia, solubilidad polímeros, soplado, soporte bateria, soporte palanca de cambios, spheripol process, s rim, srp, staining, steering boots, stress cracking resistance, stress relaxation, stress relaxations, stress strain, style styrenic block copolymers tps, sublimación 3d, suela goma natural, suela tpr, suelas espumadas, suelas tpu mas ligero, suela tr, suitecase, sujetadores, sulfato de bario, sulfonación, surfactantes, swelling, tabla polímeros transparentes, tablero de instrumentos, tablero, tackifer, tacon, tacticidad, talón de gel, talco, tama¤o de partícula, tampilla de combustible, tampografía, taninos, tanque de expansion, tanques de combustible, tanques de gasolina, tapetes, tasa de transmisión de vapor mvtr, tear strength, tecnopolímeros, teee, telerruptor, temperatura de fragilidad, temperatura m xima de servicio, temperatura mínima de servicio, temperaturas de autoignición, tensión superficial, tensile set, termoendurecibles frente a termopl sticos, termoestable, termoformado al vacío, termopl stico estir,nico elastómeros, termopl sticos vulcanizados, termopl sticos, termo plastico, termoplasticos vs tpes, termosellado, test di robinson, texturizado, tfe, tfe p, tg, tga, thermoplastic polyurethane (tpu), thermoplastic vulcanizates (tpvs), tiempo ciclo de inyección, tiempo de residencia, tier, tinas de pl stico, tipos de procesos, tnr goma natural termoplastico, todt, tornillos autorroscantes, tornillos, tpc et, tpc, tpc es, tpc et propiedades, tpcet, tpc et, tpc et, tpe generacióntpe o, tpe v, tpe, t p e, tpee, tpe e, tpe o, tpes, tpe s, tpe u, tpev, tpe v, tpi, tpo, tpu fundas y protección, tpu, tpv alto termo, tpv generación, tpv nueva generación de polímeros termopl sticos, tpv, tr sbs, tr, transmitancia, trasparentes, tratamiento de llama, tratamiento de plasticos, tratamientos de modificación de superficie, trióxido de antimonio, troubleshooting, tubos corrugados, tubos de freno de vacío, tubos termopl sticos, tvi, uhmwpe, uhmw pe, ul94, ultrasonido, umts, under the hood, unión adhesiva, urea formaldehído, usp, variaciones de brillo, vehículos el,ctricos, ventajas del moldeo por inyección para aplicaciones automotrices, vicat, vidrio molido, vinilo, virus, viscoelasticidad polim,rica, viscosidad absoluta, viscosidad aparente, viscosidad intrínseca, viscosidad relativa, viscosidad, vitrificación, vldpe, vulcanización con óxido de metal, vulcanización con azufre, vulcanización con peróxido, vulcanización con radiación, vulcanización con silanos, vulcanización de caucho, vulcanización de uretano, vulcanización din mica, vulcanización fenólica, vulcanización iónica, vulcanización inducida por luz ultravioleta, vulcanización platinica, vulcanización, vulcanizacion tpv, warpage, water injection assisted, what is tpc et, wheel arch, wollastonite, xdur pbt, xnbr, xsbr, zapato, zapatos de seguridad, zeolitas, ziegler, natta,5g
 

 

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All registered trademarks (® - © - ™) are the property of their respective owners and are used for informational purposes only, in accordance with current copyright provisions. The lyrics are property of their respective authors and we thank them for the opportunity they give us to know their free texts for illustrative and educational purposes. If you are the author of the text you are interested in and request that the text or the inclusion of other information be deleted, send an e-mail to info@mexpolimeros.com after appropriate controls. We will satisfy your request as soon as possible. may be possible. The data and illustrations in this publication are not binding and may be changed as a result of changes and / or improvements deemed necessary by the manufacturer. The aforementioned results carefully with the objective were carried out to give instructions to the end user regarding the use of the products in various stages of their use. As there are different conditions of use, the storage and signature of the preservation mexpolimeros not responsible for damages caused to the client and / or third.
All registered trademarks (® - © - ™) are the property of their respective owners and are used for informational purposes only, in accordance with current copyright provisions. The lyrics are property of their respective authors and we thank them for the opportunity they give us to know their free texts for illustrative and educational purposes. If you are the author of the text you are interested in and request that the text or the inclusion of other information be deleted, send an e-mail to info@mexpolimeros.com after appropriate controls. We will satisfy your request as soon as possible. may be possible. The data and illustrations in this publication are not binding and may be changed as a result of changes and / or improvements deemed necessary by the manufacturer. The aforementioned results carefully with the objective were carried out to give instructions to the end user regarding the use of the products in various stages of their use. As there are different conditions of use, the storage and signature of the preservation mexpolimeros not responsible for damages caused to the client and / or third.
All registered trademarks (® - © - ™) are the property of their respective owners and are used for informational purposes only, in accordance with current copyright provisions. The lyrics are property of their respective authors and we thank them for the opportunity they give us to know their free texts for illustrative and educational purposes. If you are the author of the text you are interested in and request that the text or the inclusion of other information be deleted, send an e-mail to info@mexpolimeros.com after appropriate controls. We will satisfy your request as soon as possible. may be possible. The data and illustrations in this publication are not binding and may be changed as a result of changes and / or improvements deemed necessary by the manufacturer. The aforementioned results carefully with the objective were carried out to give instructions to the end user regarding the use of the products in various stages of their use. As there are different conditions of use, the storage and signature of the preservation mexpolimeros not responsible for damages caused to the client and / or third.
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